Detail publikace

Synthesis, structure, spectral properties and DFT quantum chemical calculations of 4-aminoazobenzene dyes. Effect of intramolecular hydrogen bonding on photoisomerization

Originální název

Synthesis, structure, spectral properties and DFT quantum chemical calculations of 4-aminoazobenzene dyes. Effect of intramolecular hydrogen bonding on photoisomerization

Anglický název

Synthesis, structure, spectral properties and DFT quantum chemical calculations of 4-aminoazobenzene dyes. Effect of intramolecular hydrogen bonding on photoisomerization

Jazyk

en

Originální abstrakt

Three different “push-pull” 4-aminoazobenzene dyes with intramolecular hydrogen bonding have been synthesized. DFT quantum chemical calculations and NBO analysis of trans (E) and cis (Z) isomers have been performed. The HOMO and LUMO energy levels were calculated and experimentally estimated. The photochromic behavior was discussed in different solvent polarity. The photoisomerization has been investigated in CHCl3 and DMF.

Anglický abstrakt

Three different “push-pull” 4-aminoazobenzene dyes with intramolecular hydrogen bonding have been synthesized. DFT quantum chemical calculations and NBO analysis of trans (E) and cis (Z) isomers have been performed. The HOMO and LUMO energy levels were calculated and experimentally estimated. The photochromic behavior was discussed in different solvent polarity. The photoisomerization has been investigated in CHCl3 and DMF.

BibTex


@article{BUT145940,
  author="Ivaylo {Zhivkov} and Deyan {Dimov} and Jozef {Krajčovič} and Martin {Vala} and Martin {Weiter}",
  title="Synthesis, structure, spectral properties and DFT quantum chemical calculations of 4-aminoazobenzene dyes. Effect of intramolecular hydrogen bonding on photoisomerization",
  annote="Three different “push-pull” 4-aminoazobenzene dyes with intramolecular hydrogen bonding have been synthesized.
DFT quantum chemical calculations and NBO analysis of trans (E) and cis (Z) isomers have been performed.
The HOMO and LUMO energy levels were calculated and experimentally estimated.
The photochromic behavior was discussed in different solvent polarity.
The photoisomerization has been investigated in CHCl3 and DMF.",
  address="Elsevier",
  chapter="145940",
  doi="10.1016/j.saa.2016.12.005",
  howpublished="online",
  institution="Elsevier",
  number="1",
  volume="175",
  year="2017",
  month="march",
  pages="76--91",
  publisher="Elsevier",
  type="journal article in Web of Science"
}