Czech

Not applicable.

Solution of principles and procedures in model and real phase systems and transitions between particular phases in uniform as well as in multicomponent systems.

Physical chemistry - thermodynamics

Not applicable.

Teaching methods depend on the type of course unit as specified in the article 7 of BUT Rules for Studies and Examinations.

oral examen

1. Thermodynamic conditions of phase equilibrium
- state function
- Gibbs energy and its properties
- thermodynamic of mixing
- ideal and real solutions, phase regulation
- conservation laws in thermodynamic systems
2. Criteria of thermodynamic equilibrium
- differential and integral expression of equilibrium conditions
- basic types of phase diagrams
- geometric thermodynamic
3. Calculations and prediction of phase diagrams
- programs for calculation of phase equilibrium: THERMOCALC
- structure of databases
4. Phase diagrams in binary and ternary systems
- examples of phase equilibrium application in real systems: distillation, zone cleaning, chromatography, distillation of non-miscible liquids, coligative properties
5. Methods of experimental study of phase equilibrium
- measurable thermodynamic parameters
- methods of data collecting of phase equilibrium
- methods of data collecting of thermodynamic data
- data transfer
6. Phase formation and decomposition
- phase nucleation and growing
- spinodal phase decomposition
- diffuse and non-diffuse phase conversions
- stabile and metastable phase equilibrium
7. Phase transformations controlled by diffusion
- diffusion mechanisms
- diffusion coefficient
- simulation of diffusion processes in heterogeneous systems
8. Application of diffusion for phase creation
- carbonization
- nitridation
- phase coarsing and dissolving
- formation of protection layers
- processes during melt setting
9. Calculations and predictions of conversion evaluations controlled by diffusion
- simulation program: DICTRA
10. Calculations of chemical equilibrium
- equilibrium constant
- reaction coordinate
- homogenous and heterogeneous reactions
- examples of chemical equilibrium calculations

Not applicable.

Students will be introduced to problems of equilibrium between phases according to the detail analysis of intermolecular interactions. Consequently, they will be introduced to contemporary principles and procedures applied for numerical prediction of phase equilibrium and phase transitions. Besides theoretical principles, real systems will be discussed with which students could probably meet in praxis.

none

Not applicable.

Not applicable.

Porter, David A. Phase Transformations in Metal and Alloys. New York : Van Nostrand Reinhol, 1981. 445 s. ISBN 0-442-30439-0 (CS)
Saunders, Nigel - Miodownik, Peter A. Calphad : calculation of phase diagrams : a comprehensive guide. Oxford : Pergamon, 1998. xvi, 479 s. Pergamon materials series; vol. 1. ISBN 0-08-042129-6. (CS)

Not applicable.

0 hours, optionally