Czech

4

Not applicable.

Basic definitions and concepts in supramolecular chemistry.

Organic chemistry, Biochemistry and Physical chemistry knowledge.

Not applicable.

Teaching methods depend on the type of course unit as specified in the article 7 of BUT Rules for Studies and Examinations.

Exam: oral

Concept and definition - clasification of supramolecular host-guest systems; receptors, coordination, key-lock analogy, chelate and macrocyclic effect; preorganisation and complementarity; thermodynamic and kinetic selectivity; nature of supramolecular interactions; supramolecular host design
Supramolecular chemistry of biological systems - alkali metal cations in biochemistry (membrane potenial and transport); rhodopsin A - a supramolecular pigment; porphyrines and other macrocycles, neurotransmiters and hormones; biochemical self-assembled systems.
Concept and definition (historical perpectives, basic concepts and terminology, applications)
Supramolecular interactions (non covalent interacions of ionic, polar and polarizable particles, van der Waals interactions, specific interactions)
Supramolecular chemistry of water (historical perspectives, water anomalies, water molecule, structure of solid and liquid water, water in living organims)
Supramolecular chemistry of biological systems (membrane potential and transport, supramolecular features of photosynthesis and respiration, enzymes, nucleic acids, natural self-assembly systems)
Synthetic ionophores (complexation of cations and anions, lcrown ethers and other corands, cryptands and spherands, calixarenes)
Binding of neutral species (inclusion compounds , cavitands, carbon nanoparticles)
Self-assembly in liquids (tenzides, liquid crystals, ionic liquids)
Supramolecular devices and machines (supramolecular sensors, electronic, photonic and mechanical devices)

Not applicable.

The aim is to provide the basic awareness on supramolecular chemistry, on design and applications of supramolecular systems.

not

Not applicable.

Not applicable.

Lehn J. - M.: Supramolecular chemistry. Wiley-VCH, Weinheim 1995. (CS)
Ariga K., Kunitake T.: Supramolecular chemistry: fundamentals and applications: advanced textbook. Springer, Berlin 2005. (CS)
Schalley, C.: Analytical Methods in Supramolecular Chemistry. Wiley-VCH Verlag 2007 (CS)

Steed J. W., Atwood J. L.: Supramolecular chemistry. John Wiley & Sons Ltd, Chichester 2000. (CS)

13 hours, optionally