Czech

6

Not applicable.

Completing the course, students should obtain more complex view on problems of chemical kinetics. Finishing the studies at the Faculty, they should be able to solve the problems in the field of chemical kinetics in laboratory or industrial practice.

Basic knowledge from chemical kinetics, obtained within the subject Physical chemistry II., Basic knowledge of differentiation and integration.

Not applicable.

Teaching methods depend on the type of course unit as specified in the article 7 of BUT Rules for Studies and Examinations.

Combined examination
1. Written examination : calculation of 4 problems (condition for access to oral examination -2 points from 4 must be attained)-
2.Oral examination - 4 questions

1. Relation between termodynamics and chemical kinetics, definition of reaction rate.
2. Theory of elementary reactions, of zero, 1. and 2. order; 2.order reactions of general type aA + bB = pP + rR
3. Complex reactions - reversible, paralell and consecutive. reactions; reactions involoving pre-equilibria.
4. Chain reactions, kinetic analysis of radical chain reaction H2 + Br2 = 2 HBr, kinetics of radical polymerization and polycondensation.
5. Photochemical reactions, kinetics of photochemical reactions, kinetics of quenching - Stern-Volmer equation
6. Dependence of reaction rate on temperature and pressure.Theory of activated complex, thermodynamic formulation of rate constant.
7. Theory of activated complex, applied to reactions in solution - the influence of dielectric constant on reaction rate, the influence of structure - Hammett equations
8. Theory of homogeneous catalysis, acid-base catalysis, autocatalysis.
9. Enzyme catalysis - kinetic analysis of noninhibitited and inhibited enzyme reactions.
10. Theory of heterogeneous catalysis, Langmuir isotherm for adsorption with and without dissociation. Langmuir-Hinshellwood and Eyel-Rideal mechanism of surface reaction.
11. Kinetic analysis of heterogeneously catalyzed mono and bimolecular reactions. Experimental activation energy in heterogeneous catalysis, its relation to activation energies of partial processes.

Not applicable.

The goal of the subject is the improvement of knowledge of basic course of chemical kinetics, presented within Physical Chemistry II. Students are aquainted with the kinetic analysis of reactions, which is in comparison with basic course substantially more sophisticated from mathematical point of view.

none

Not applicable.

Not applicable.

Fogler H.S.: Elements of Chemical Reaction Engineering (EN)
Kraus M.: Chemická kinetika pro inženýry (CS)
Eckert: Aplikovaná chemická kinetika (CS)

Atkins P. W.: Fyzikálna chémia. Oxford/STU Bratislava, Bratislava 1999. (CS)
Treindl L.: Chemická kinetika. SPN Bratislava 1978. (CS)
House J.E.: Principles of chemical kinetics, Elsevier, 2007 (CS)

26 hours, compulsory