Publication detail

Ternary and Quaternary Nanocrystalline Cu-Based Sulfides as Perspective Antibacterial Materials Mechanochemically Synthesized in a Scalable Fashion

BALÁŽ, M. TKÁČIKOVÁ, L. STAHORSKÝ, M. CASAS LUNA, M. DUTKOVÁ, E. ČELKO, L. KOVÁČOVÁ, M. ACHIMOVIČOVÁ, M. BALÁŽ, P.

Original Title

Ternary and Quaternary Nanocrystalline Cu-Based Sulfides as Perspective Antibacterial Materials Mechanochemically Synthesized in a Scalable Fashion

Type

journal article in Web of Science

Language

English

Original Abstract

Twelve Cu-based ternary (Cu-Me1-S, Me1 = Fe, Sn, or Sb) and quaternary (Cu-Me2-Sn-S, Me2 = Fe, Zn, or V) nanocrystalline sulfides are shown as perspective antibacterial materials here. They were prepared from elemental precursors by a one-step solvent-free mechanochemical synthesis in a 100 g batch using scalable eccentric vibratory ball milling. Most of the products have shown strong antibacterial activity against Escherichia coli and Staphylococcus aureus bacteria. For instance, stannite Cu2FeSnS4 and mohite Cu2SnS3 were the most active against E. coli, whereas kesterite Cu2ZnSnS4 and rhodostannite Cu2FeSn3S8 exhibited the highest antibacterial activity against S. aureus. In general, stannite has shown the best antibacterial properties out of all the studied samples. Five out of twelve products have been prepared using mechanochemical synthesis for the first time in a scalable fashion here. The presented synthetic approach is a promising alternative to traditional syntheses of nanomaterials suitable for biological applications and shows ternary and quaternary sulfides as potential candidates for the next-generation antibacterial agents. © 2022 American Chemical Society.

Keywords

Cu-based nanocrystalline sulfides; antibacterial materials; mechanochemical synthesis

Authors

BALÁŽ, M.; TKÁČIKOVÁ, L.; STAHORSKÝ, M.; CASAS LUNA, M.; DUTKOVÁ, E.; ČELKO, L.; KOVÁČOVÁ, M.; ACHIMOVIČOVÁ, M.; BALÁŽ, P.

Released

26. 6. 2022

Publisher

Americal Chemical Society

Location

Washington, DC

ISBN

2470-1343

Periodical

ACS OMEGA

Number

7

State

United States of America

Pages from

27164

Pages to

27171

Pages count

8

URL

BibTex

@article{BUT179183,
  author="BALÁŽ, M. and TKÁČIKOVÁ, L. and STAHORSKÝ, M. and CASAS LUNA, M. and DUTKOVÁ, E. and ČELKO, L. and KOVÁČOVÁ, M. and ACHIMOVIČOVÁ, M. and BALÁŽ, P.",
  title="Ternary and Quaternary Nanocrystalline Cu-Based Sulfides as Perspective Antibacterial Materials Mechanochemically Synthesized in a Scalable Fashion",
  journal="ACS OMEGA",
  year="2022",
  number="7",
  pages="27164--27171",
  doi="10.1021/acsomega.2c01657",
  issn="2470-1343",
  url="https://pubs.acs.org/doi/10.1021/acsomega.2c01657?ref=pdf"
}