Publication detail

Comprehensive Study of Novel Adamantane Asymmetrically-Substituted Diketopyrrolopyrrole Derivatives

CIGÁNEK, M. HEINRICHOVÁ, P. KUČERÍK, J. KRAJČOVIČ, J.

Original Title

Comprehensive Study of Novel Adamantane Asymmetrically-Substituted Diketopyrrolopyrrole Derivatives

English Title

Comprehensive Study of Novel Adamantane Asymmetrically-Substituted Diketopyrrolopyrrole Derivatives

Type

abstract

Language

en

Original Abstract

The series of three DPP derivatives was prepared by nucleophilic substitution of 1-(2-bromoethyl)adamantane chains. The main aim of this work was to focus on isolation of all three possible formed products (NN-; N,O- and O,O-alkylated) and investigate their properties. In this work it was discovered that adamantyl chains has a significant role in the crystallinity of O-alkylated derivative. Furthermore, optical properties were investigated for all prepared derivatives, both in solution and in thin layers. The position of alkyl chains in the DPP molecule significantly affected both absorption and fluorescence emission spectra. The thermal stability of N- and O-alkylated derivatives also differed significantly.

English abstract

The series of three DPP derivatives was prepared by nucleophilic substitution of 1-(2-bromoethyl)adamantane chains. The main aim of this work was to focus on isolation of all three possible formed products (NN-; N,O- and O,O-alkylated) and investigate their properties. In this work it was discovered that adamantyl chains has a significant role in the crystallinity of O-alkylated derivative. Furthermore, optical properties were investigated for all prepared derivatives, both in solution and in thin layers. The position of alkyl chains in the DPP molecule significantly affected both absorption and fluorescence emission spectra. The thermal stability of N- and O-alkylated derivatives also differed significantly.

Keywords

diketopyrrolopyrrole; asymmetrical alkylation; adamantyl

Released

21.11.2019

Publisher

Vysoké učení technické v Brně, Fakulta chemická

Location

Brno

ISBN

978-80-214-5807-9

Book

Studentská odborná konference Chemie je život 2019

Edition

první

Pages from

72

Pages to

72

Pages count

1

Documents

BibTex


@misc{BUT160834,
  author="Martin {Cigánek} and Patricie {Heinrichová} and Jiří {Kučerík} and Jozef {Krajčovič}",
  title="Comprehensive Study of Novel Adamantane Asymmetrically-Substituted Diketopyrrolopyrrole Derivatives",
  annote="The series of three DPP derivatives was prepared by nucleophilic substitution of 1-(2-bromoethyl)adamantane chains. The main aim of this work was to focus on isolation of all three possible formed products (NN-; N,O- and O,O-alkylated) and investigate their properties. In this work it was discovered that adamantyl chains has a significant role in the crystallinity of O-alkylated derivative. Furthermore, optical properties were investigated for all prepared derivatives, both in solution and in thin layers. The position of alkyl chains in the DPP molecule significantly affected both absorption and fluorescence emission spectra. The thermal stability of N- and O-alkylated derivatives also differed significantly.",
  address="Vysoké učení technické v Brně, Fakulta chemická",
  booktitle="Studentská odborná konference Chemie je život 2019",
  chapter="160834",
  edition="první",
  howpublished="print",
  institution="Vysoké učení technické v Brně, Fakulta chemická",
  year="2019",
  month="november",
  pages="72--72",
  publisher="Vysoké učení technické v Brně, Fakulta chemická",
  type="abstract"
}