Publication detail

Viscosities, Densities, and Refractive Indices of Aqueous Propane-1,3-diol

MIKŠÍK, F. KOTLÍK, J. SKOLIL, J. PŮČKOVÁ, H. ČÁSLAVSKÝ, J. MIYAZAKI, T KAČÍRKOVÁ, M

Original Title

Viscosities, Densities, and Refractive Indices of Aqueous Propane-1,3-diol

Type

journal article in Web of Science

Language

English

Original Abstract

A detailed investigation into the viscosity, density, and refractive index of a binary mixture of propane-1,3-diol/water was performed for the whole range of mass fractions of propane-1,3-diol. The viscosity and density were measured over a wide range of temperatures from T = 253.15 K to T = 353.15 K where possible, or to the nearest safe point before freezing. The refractive indices were measured for the same dilutions as in the case of the viscosity and density over a reduced temperature range of T = (278.15 to 318.15) K. A mathematical analysis via excess properties was conducted and fitted to the Redlich–Kister equation. Furthermore, a prediction of density data is provided by a polynomial and DIPPR exponential model. The viscosity data are fitted to Grunberg-Nissan, Lederer, McAllister, and Heric models and a new combined model with variable temperature and molar and mass fractions based on these models is presented. Data comparison of the propane-1,3-diol/water binary mixture is performed on propan-1,2-diol/water mixture as the physically closest binary system and application alternative fluid.

Keywords

propane-1,3-diol, propan-1,2-diol, viscosity, density, refractive index, Aqueous

Authors

MIKŠÍK, F.; KOTLÍK, J.; SKOLIL, J.; PŮČKOVÁ, H.; ČÁSLAVSKÝ, J.; MIYAZAKI, T; KAČÍRKOVÁ, M

Released

16. 11. 2018

Publisher

Cockrell Family Chair in Engineering #16

Location

McKetta Department of Chemical Engineering The University of Texas at Austin USA

ISBN

1520-5134

Periodical

Journal of Chemical & Engineering Data

Year of study

63

Number

12

State

United States of America

Pages from

4350

Pages to

4367

Pages count

17

URL

https://pubs.acs.org/doi/ipdf/10.1021/acs.jced.8b00403

BibTex

@article{BUT152131,
  author="MIKŠÍK, F. and KOTLÍK, J. and SKOLIL, J. and PŮČKOVÁ, H. and ČÁSLAVSKÝ, J. and MIYAZAKI, T and KAČÍRKOVÁ, M",
  title="Viscosities, Densities, and Refractive Indices of Aqueous Propane-1,3-diol",
  journal="Journal of Chemical & Engineering Data",
  year="2018",
  volume="63",
  number="12",
  pages="4350--4367",
  doi="10.1021/acs.jced.8b00403",
  issn="1520-5134",
  url="https://pubs.acs.org/doi/ipdf/10.1021/acs.jced.8b00403"
}