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CLAROS VARGAS, M. JIMENEZ Y.P.. CORTES, S.
Original Title
Water activities of ternaty mixtures of poly(ethylene glycol), Fe2(SO4)3 and water ocer the temperature range of 303.15 to 333.15 K
Type
journal article in Web of Science
Language
English
Original Abstract
The thermodynamic behavior of aqueous solutions containing the solutes ferric sulfate and poly(ethylene glycol) with an average molecular weight of 4000 (PEG 4000) was studied. These three compounds are vital components for forming the aqueous two-phase system. Consecuently, the water activity of the ternary system at 303.15, 313.15, 323.15 and 333.15K were determined, using vapor pressure osmometry. The concentratio of PEG was fixed to 0.05,0.1,0.15 and 0.2 mass fraction whereas the salt concentration was fixed to 0.05, 0.075, 0.1, 0.125, 0.15, 0.175 and 0.2 mass fraction. Additionally, the water activities of the constituent binary system (Fe2(SO)3+H2O) were measured in the same temperature range for different salt concentratiosn. The results show that ferric sulfate has a significatn effect on the wter activity in the salt-PEG-water system. From these measurements, values of the vapor pressure of solutions were determined. Finally, the experimetnal data were corraleted with the UNIQUAC model, obtaining a good agreement between experimental and correlated data.
Keywords
Water activity; Poly(ethylene glycol); ferric sulfate; aqueous-two phase system
Authors
CLAROS VARGAS, M.; JIMENEZ Y.P..; CORTES, S.
Released
15. 6. 2019
Publisher
Journal of Molecular Liquids
Location
Netherlands
ISBN
0167-7322
Periodical
JOURNAL OF MOLECULAR LIQUIDS
Year of study
284
Number
01677322
State
Kingdom of the Netherlands
Pages from
45
Pages to
52
Pages count
8
URL
http://sciencedirect.com/science/article/pii/S0167732218364729
BibTex
@article{BUT160571, author="CLAROS VARGAS, M. and JIMENEZ Y.P.. and CORTES, S.", title="Water activities of ternaty mixtures of poly(ethylene glycol), Fe2(SO4)3 and water ocer the temperature range of 303.15 to 333.15 K", journal="JOURNAL OF MOLECULAR LIQUIDS", year="2019", volume="284", number="01677322", pages="45--52", doi="10.1016/j.molliq.2019.03.110", issn="0167-7322", url="http://sciencedirect.com/science/article/pii/S0167732218364729" }