Publication detail

High-Spin Mononuclear Iron(III) Complexes with Pentadentate Schiff Base Ligands: Structural Analysis and Magnetic Properties

POGÁNY, L. MONCOL, J. PAVLIK, J. MAZÚR, M. ŠALITROŠ, I.

Original Title

High-Spin Mononuclear Iron(III) Complexes with Pentadentate Schiff Base Ligands: Structural Analysis and Magnetic Properties

Type

journal article in Web of Science

Language

English

Original Abstract

Various substituted 2-hydroxybenzophenones were combined with aliphatic linear triamines to form pentadentate Schiff base ligands. Twelve new iron(III) complexes with the general formula [Fe(Ln)X].mCH3CN (n=1–10; X=N3 @, NCS@ or NCSe@; m=0–2) have been synthesized, and spectrally as well as structurally characterized. The structural analysis revealed a notable dependence of coordination polyhedra deformation as well as the spatial configuration of donor atoms on the length and symmetry of the Schiff base ligands. The magnetic properties of the compounds were investigated and the permanent high-spin state (S=5/2) for all reported compounds was established, and allowed calculation of zero-field-splitting parameters as well as coupling constants, which were further confirmed with DFT calculations. The solid-state EPR spectra were recorded at 293 K and 98 K, and in accordance with the magnetic measurements, showed a high-spin state in the measured temperature range.

Keywords

density functional calculations; iron(III) complexes; magnetic properties; N; O-ligands; Schiff bases

Authors

POGÁNY, L.; MONCOL, J.; PAVLIK, J.; MAZÚR, M.; ŠALITROŠ, I.

Released

1. 4. 2019

ISBN

2192-6506

Periodical

ChemPlusChem

Year of study

84

Number

4

State

Federal Republic of Germany

Pages from

358

Pages to

367

Pages count

10

URL

https://onlinelibrary.wiley.com/doi/full/10.1002/cplu.201800658

BibTex

@article{BUT156514,
  author="Lukáš {Pogány} and Ján {Moncol} and Ján {Pavlik} and Milan {Mazúr} and Ivan {Šalitroš}",
  title="High-Spin Mononuclear Iron(III) Complexes with Pentadentate Schiff Base Ligands: Structural Analysis and
Magnetic Properties",
  journal="ChemPlusChem",
  year="2019",
  volume="84",
  number="4",
  pages="358--367",
  doi="10.1002/cplu.201800658",
  issn="2192-6506",
  url="https://onlinelibrary.wiley.com/doi/full/10.1002/cplu.201800658"
}