Detail publikace

SYNTHESIS OF CONJUGATED AROMATIC SYSTEMS AND THEIR PROPERTIES

BRHELOVÁ, M. SEMRÁD, H. MUNZAROVÁ, M. PILAŘOVÁ, I. TRNKOVÁ, L. POTÁČEK, M.

Originální název

SYNTHESIS OF CONJUGATED AROMATIC SYSTEMS AND THEIR PROPERTIES

Typ

článek ve sborníku ve WoS nebo Scopus

Jazyk

angličtina

Originální abstrakt

The presented paper deals with the synthesis of conjugated systems consisted from phenyl, thiophene or mixed phenyl and thiophene units, substituted on the ends to create molecules with push-pull delocalized pi-electronic orbital system. The synthesis is based upon application of modern Suzuki-Miyaura coupling reaction. This reaction represents break down in reactivity of halogen at aromatic hydrocarbon. Using aromatic boronic acids in the reaction with halogen containing aromatic skeleton, in the presence of homogenous palladium catalyst and presence of a base, biaryl compound is synthesized. The prepared new compounds underwent examination on their physical-chemical properties. Their UV and fluorescence spectra are presented, cyclic voltammetry was carried out, and basic quantum chemistry calculations are submitted. Based on this data possible application is displayed.

Klíčová slova

conjugated aromatic systems; Suzuki-Miyaura coupling reaction; fluorescence spectra; HOMO and LUMO energies

Autoři

BRHELOVÁ, M.; SEMRÁD, H.; MUNZAROVÁ, M.; PILAŘOVÁ, I.; TRNKOVÁ, L.; POTÁČEK, M.

Rok RIV

2015

Vydáno

26. 5. 2015

Nakladatel

Masaryk University

Místo

Brno

ISBN

978-80-210-7857-4

Kniha

XV. Workshop of Physical Chemists and Electrochemists

Edice

1

Strany od

137

Strany do

141

Strany počet

5

BibTex

@inproceedings{BUT120387,
  author="Michaela {Brhelová} and Hugo {Semrád} and Markéta {Munzarová} and Iveta {Pilařová} and Libuše {Trnková} and Milan {Potáček}",
  title="SYNTHESIS OF CONJUGATED AROMATIC SYSTEMS AND THEIR PROPERTIES",
  booktitle="XV. Workshop of Physical Chemists and Electrochemists",
  year="2015",
  series="1",
  pages="137--141",
  publisher="Masaryk University",
  address="Brno",
  isbn="978-80-210-7857-4"
}