Detail publikace

The non-isothermal kinetics analysis of the thermal decomposition of kaolinite by Effluent Gas Analysis technique

PTÁČEK, P. ŠOUKAL, F. OPRAVIL, T. KŘEČKOVÁ, M. HAVLICA, J. BRANDŠTETR, J.

Originální název

The non-isothermal kinetics analysis of the thermal decomposition of kaolinite by Effluent Gas Analysis technique

Anglický název

The non-isothermal kinetics analysis of the thermal decomposition of kaolinite by Effluent Gas Analysis technique

Jazyk

en

Originální abstrakt

The thermal decomposition of kaolin with high-content of the medium ordered kaolinite was studied by Effluent Gas Analysis (EGA) under non-isothermal conditions. This technique enables to distinguish two overlaying processes during the thermal decomposition of kaolin: oxidation of organic compounds and dehydroxylation. The kinetic of non-isothermal dehydroxylation of kaolinite is controlled by the rate of the third-order reaction. For the given reaction mechanism, the overall activation energy (EA) and pre-exponential (frequency) factor (A) values are 242 kJ mol-1 and 2.21 . 10E8 s-1, respectively.

Anglický abstrakt

The thermal decomposition of kaolin with high-content of the medium ordered kaolinite was studied by Effluent Gas Analysis (EGA) under non-isothermal conditions. This technique enables to distinguish two overlaying processes during the thermal decomposition of kaolin: oxidation of organic compounds and dehydroxylation. The kinetic of non-isothermal dehydroxylation of kaolinite is controlled by the rate of the third-order reaction. For the given reaction mechanism, the overall activation energy (EA) and pre-exponential (frequency) factor (A) values are 242 kJ mol-1 and 2.21 . 10E8 s-1, respectively.

Dokumenty

BibTex 


@article{BUT51017,
  author="Petr {Ptáček} and František {Šoukal} and Tomáš {Opravil} and Magdaléna {Křečková} and Jaromír {Havlica} and Jiří {Brandštetr}",
  title="The non-isothermal kinetics analysis of the thermal decomposition of kaolinite by Effluent Gas Analysis technique",
  annote="The thermal decomposition of kaolin with high-content of the medium ordered kaolinite was studied by Effluent Gas Analysis (EGA) under non-isothermal conditions. This technique enables to distinguish two overlaying processes during the thermal decomposition of kaolin: oxidation of organic compounds and dehydroxylation. The kinetic of non-isothermal dehydroxylation of kaolinite is controlled by the rate of the third-order reaction. For the given reaction mechanism, the overall activation energy (EA) and pre-exponential (frequency) factor (A) values are 242 kJ mol-1 and 2.21 . 10E8 s-1, respectively.",
  address="Elsevier",
  chapter="51017",
  institution="Elsevier",
  number="2",
  volume="203",
  year="2010",
  month="november",
  pages="272--276",
  publisher="Elsevier",
  type="journal article in Web of Science"
}