Detail publikace

Synthesis and Crystal Structure of the First Selenonyl Bis(carboxylate) SeO2(O2CCH3)(2)

RICHTERA, L. JANČÍK, V. BARROSO-FLORES, J. NYKEL, P. TOUŽÍN, J. TARABA, J.

Originální název

Synthesis and Crystal Structure of the First Selenonyl Bis(carboxylate) SeO2(O2CCH3)(2)

Typ

článek v časopise ve Web of Science, Jimp

Jazyk

angličtina

Originální abstrakt

Analytically pure selenonyl bis(acetate) SeO2(O2CCH3)(2) was prepared by the reaction of SeO3 with a stoichiometric amount of acetic anhydride in nitromethane; it crystallizes in the monoclinic P2(1)/n space group with one molecule in the asymmetric unit and a = 5.2044(1) angstrom, b = 21.6580(5) angstrom, c = 6.7074(2) angstrom, and = 93.628(2)degrees. The selenium atom binds to two oxo groups and two acetate anions in a distorted tetrahedral geometry. Analysis of the Hirschfeld surface indicated the presence of numerous C-HO interactions.

Klíčová slova

Main group elements; Selenium; Structure elucidation; Hirschfeld surface

Autoři

RICHTERA, L.; JANČÍK, V.; BARROSO-FLORES, J.; NYKEL, P.; TOUŽÍN, J.; TARABA, J.

Vydáno

1. 6. 2015

ISSN

1434-1948

Periodikum

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Ročník

18

Číslo

1

Stát

Spolková republika Německo

Strany od

2923

Strany do

2927

Strany počet

5

BibTex

@article{BUT145353,
  author="RICHTERA, L. and JANČÍK, V. and BARROSO-FLORES, J. and NYKEL, P. and TOUŽÍN, J. and TARABA, J.",
  title="Synthesis and Crystal Structure of the First Selenonyl Bis(carboxylate) SeO2(O2CCH3)(2)",
  journal="EUROPEAN JOURNAL OF INORGANIC CHEMISTRY",
  year="2015",
  volume="18",
  number="1",
  pages="2923--2927",
  doi="10.1002/ejic.201500271",
  issn="1434-1948"
}