Detail publikace

Synthesis, crystal structure and magnetic properties of trithiocyanurate or thiodiacetate polynuclear Ni(II) and Co(II) complexes

BIEŃKO, A. KOPEL, P. KIZEK, R. KRUSZYŃSKI, R. BIEŃKO, D. TIFIŠ, J. BOČA, R.

Originální název

Synthesis, crystal structure and magnetic properties of trithiocyanurate or thiodiacetate polynuclear Ni(II) and Co(II) complexes

Typ

článek v časopise ve Web of Science, Jimp

Jazyk

angličtina

Originální abstrakt

Magnetism of high-nuclearity complexes is currently an active field of research since it was discovered that a M12 complex exhibits single-molecule magnet (SMM) behavior [1]. However, the synthesis f such species is challenging. The synthetic route is to carefully select the bridging ligands and control the hydrolysis or alcoholysis of metal ions in the presence of auxiliary ligands. The compounds can be bridged by single atoms as well as by polyatomic bridges.The magnetic susceptibilities of all antiferromagnetic complexes were fitted by using approximate models.

Klíčová slova

Nickel, Cobalt, Bridging ligand, Multinuclear complexes, Magnetic properties

Autoři

BIEŃKO, A.; KOPEL, P.; KIZEK, R.; KRUSZYŃSKI, R.; BIEŃKO, D.; TIFIŠ, J.; BOČA, R.

Rok RIV

2014

Vydáno

24. 5. 2014

ISSN

0020-1693

Periodikum

INORGANICA CHIMICA ACTA

Ročník

416

Číslo

1

Stát

Švýcarská konfederace

Strany od

147

Strany do

156

Strany počet

10

BibTex

@article{BUT112332,
  author="Alina {Bieńko} and Pavel {Kopel} and René {Kizek} and Rafał {Kruszyński} and Dariusz {Bieńko} and Ján {Tifiš} and Roman {Boča}",
  title="Synthesis, crystal structure and magnetic properties of trithiocyanurate or thiodiacetate polynuclear Ni(II) and Co(II) complexes",
  journal="INORGANICA CHIMICA ACTA",
  year="2014",
  volume="416",
  number="1",
  pages="147--156",
  doi="10.1016/j.ica.2014.03.009",
  issn="0020-1693"
}