Detail publikace

A Mn(III) single ion magnet with tridentate Schiff-base ligands

S. Realista, A. J. Fitzpatrick, G. Santos, L. P. Ferreira, S. Barroso, L. C. J. Pereira, N. A. G. Bandeira, P. Neugebauer, J. Hrubý, G. G. Morgan, J. van Slageren, M. J. Calhordaa and P. N. Martinho

Originální název

A Mn(III) single ion magnet with tridentate Schiff-base ligands

Typ

článek v časopise ve Web of Science, Jimp

Jazyk

angličtina

Originální abstrakt

Single ion magnet behaviour is reported for a mononuclear Mn(III) ion with tridentate Schiff-base ligands which exhibits a tetragonal Jahn–Teller elongation along the Namine–Mn–Namine axis and crystallises with two crystallographically distinct Mn(III) cations (unit A and unit B). While magnetic measurements show a large and negative axial zero-field splitting (D = −4.73 cm−1), HF-EPR reveal two distinct large axial Ds (D = −4.60 cm−1 for unit A and D = −4.18 cm−1 for unit B), thus resulting in the largest D known to date for a Mn(III) single ion magnet. AC magnetic measurements at 2000 Oe allowed determination of the energy barrier for spin reversal (10.19 K) and spin reversal relaxation time (1.476 × 10−6 s) for the Mn(III) ion. Computational studies were used to characterise the electronic structure and substantiate the zero field splitting in the Mn(III) complex.

Klíčová slova

single-molecule magnets, inorganic chemistry

Autoři

S. Realista, A. J. Fitzpatrick, G. Santos, L. P. Ferreira, S. Barroso, L. C. J. Pereira, N. A. G. Bandeira, P. Neugebauer, J. Hrubý, G. G. Morgan, J. van Slageren, M. J. Calhordaa and P. N. Martinho

Vydáno

13. 7. 2016

ISSN

1477-9234

Periodikum

Dalton Transactions

Ročník

31

Číslo

45

Stát

Spojené království Velké Británie a Severního Irska

Strany od

12301

Strany do

12307

Strany počet

7

URL

http://pubs.rsc.org/en/content/articlelanding/2016/dt/c6dt02538b#!divAbstract

BibTex

@article{BUT145623,
  author="Jakub {Hrubý} and Petr {Neugebauer}",
  title="A Mn(III) single ion magnet with tridentate Schiff-base ligands",
  journal="Dalton Transactions",
  year="2016",
  volume="31",
  number="45",
  pages="12301--12307",
  doi="10.1039/C6DT02538B",
  issn="1477-9234",
  url="http://pubs.rsc.org/en/content/articlelanding/2016/dt/c6dt02538b#!divAbstract"
}