Detail předmětu

Koordinační chemie a molekulární magnetismus

CEITEC VUT-DS121Ak. rok: 2020/2021


Introduction to coordination chemistry
– striking difference
– historical background

Fundamentals of Structure and Bonding
– atomic orbitals
– molecular orbitals

18-Electron Rule
– counting electrons
– why 18 electrons?
– square planar complexes

Carbonyl and Pi Ligands
– Pi bonding
– oxygen-bonded carbonyls
– ligands similar to CO
– linear Pi systems
– cyclic Pi systems
– infrared and NMR spectra of organometallic compounds

Organometallic reactions I
– reactions that occur at the metal
– ligand substitution
– oxidative addition
– reductive elimination

Organometallic reactions II
– reaction involving modification of ligands
– insertion and deinsertion
– nucleophilic addition to the ligand
– nucleophilic abstraction and electrophilic reactions

Application of coordination chemistry to molecular magnetism
– electronic structure of coordinated ions
– design single-ions
– the crystal field

Toward the Molecular Ferromagnetism
– magnetic Interactions
– spin Hamiltonians and multicenter interactions

Structure and properties of p, d and f coupled systems
– magnetic coupling in organics
– magnetism in nitroxides
– metallorganic magnets

Single Molecular Magnets SMM
– Mn12 – the start
– Fe4 structure and magnetic properties
– SMM with Lanthanides

Garant předmětu

Doporučená nebo povinná literatura

J. R. Gispert – Coordination Chemistry, Wiley-VCH Verlag GmbH, 2008 (EN)
M. Weller, T. Overton , Jonathan Rourke, Fraser Armstrong – Inorganic Chemistry, Oxford University Press, 2018. (EN)
R. A. Layfield, M. Murugesu – Lanthanides and Actinides in Molecular Magnetism, Wiley-VCH Verlag GmbH & Co. KGaA, 2015. (EN)
C. Benelli, D. Gatteschi – Introduction to Molecular Magnetism: From Transition Metals to Lanthanides, Wiley‐VCH Verlag GmbH & Co. KGaA, 2015. (EN)
J. S. Griffith – The Theory of Transition-Metal Ions, Cambridge University Press, 1980. (EN)
B. S. Tsukerblat – Group Theory in Chemistry and Spectroscopy, Dover Publication, Inc. 2006. (EN)
D. Gatteschi, R. Sessoli, J. Villain – Molecular Nanomagnets, Oxford University Press, 2011. (EN)

Plánované vzdělávací činnosti a výukové metody

block of lectures in one week

Jazyk výuky

angličtina

Cíl

The aim of the course is to provide the students the basic concept of coordination chemistry and its relation to molecular magnetism:

Zařazení předmětu ve studijních plánech

  • Program STIAMN doktorský

    obor AM , 1. ročník, letní semestr, 0 kreditů, povinně volitelný
    obor ANTMT , 1. ročník, letní semestr, 0 kreditů, povinně volitelný