Course detail

Photoinduced processes in molecular materials

FCH-DCO_FPDAcad. year: 2019/2020

The course is focused on the interaction of photons with organic molecules, molecular crystals and polymers. The primary processes of optical absorption, fluorescence, phosphorescence, non-radiative transitions and generation of excited species, such as excitons, excimers, exciplexes and photoinduced charge transfer states, are discussed in detail. The explanation of basic terms is followed by a complex analysis of photophysical and photochemical processes, such as photochromism, photoconductivity, electroluminescence, photodielectric effect, excitation energy transfer, photosynthesis, photodegradation of materials and some non-linear optical effects. From the application point of view, the principles of basic molecular optoelectronic elements, such as optical memories, photodetectors, solar cells, electroluminescent displays and non-linear optical elements (photorefractive and holographic memories) are discussed. From the chemical point of view, examples are mentioned of relations of molecular structures, physical and chemical properties of materials, types of basic chemical syntheses, and modifications of low-molecular-weight and polymer materials.

Learning outcomes of the course unit

Knowledge of selected photophysical and photochemical phenomenon.

Prerequisites

Basic knowledge from organic chemistry and solid state physics (basic course).

Co-requisites

Not applicable.

Recommended optional programme components

Not applicable.

Recommended or required reading

N. J. Turro, Modern Molecular Photochemistry, The Benjamin/Cummings Publishing Company, inc., London, 1991 (EN)
J-L Bredas, S. R. Marder, Organic Semiconductors, World Scientific, London, 2016 (EN)
N. V. Tkachenko, Optical Spectroscopy Methods and Instrumentation, Elsevier, Amsterdam, 2006 (EN)
S. A. Jenekhe, K. J. Wynne, Photonic and optoelectronic polymers, American Chemical Society, Washington, 1995 (EN)
J. B. Birks, Photophysics of aromatic molecules, Wiiley-Interscience, London, 1970 (EN)

Planned learning activities and teaching methods

The course uses teaching methods in form of lectures and individual consultation. The e-learning system (LMS Moodle) is available to teachers and students. Individual work of students consists of working out a semester work on a selected topic related to the focus of his / her dissertation.

Assesment methods and criteria linked to learning outcomes

Not applicable.

Language of instruction

Czech

Work placements

Not applicable.

Course curriculum

The course is focused on the interaction of photons with organic molecules, molecular crystals and polymers. The primary processes of optical absorption, fluorescence, phosphorescence, non-radiative transitions and generation of excited species, such as excitons, excimers, exciplexes and photoinduced charge transfer states, are discussed in detail. The explanation of basic terms is followed by a complex analysis of photophysical and photochemical processes, such as photochromism, photoconductivity, electroluminescence, photodielectric effect, excitation energy transfer, photosynthesis, photodegradation of materials and some non-linear optical effects. From the application point of view, the principles of basic molecular optoelectronic elements, such as optical memories, photodetectors, solar cells, electroluminescent displays and non-linear optical elements (photorefractive and holographic memories) are discussed. From the chemical point of view, examples are mentioned of relations of molecular structures, physical and chemical properties of materials, types of basic chemical syntheses, and modifications of low-molecular-weight and polymer materials.

Light and material
Optical properties of molecules
Electronic structure of molecular materials
Absorption, fluorescence, phosphorescence, non-radiative transitions
Excitons, excimers, exciplexes, charge-transfer states
Photochromism and photoconductivity
Photosynthesis
Excitation energy transfer
Nonlinear optics
Electroluminescence and photodielectric effect
Optoelectronic elements, optical memories
Material photodegradation
Basic photochemical and photophysical experimental methods

Aims

The aim of the course is to get knowledge and experience in the field of principles of the interaction of light with materials and related photophysical and photochemical processes primarilly in molecular meterials.

Specification of controlled education, way of implementation and compensation for absences

none

Classification of course in study plans

  • Programme DPAP_CHM_4 Doctoral

    branch DPAO_CHM_4 , 1. year of study, winter semester, 0 credits, compulsory-optional

  • Programme DKAP_CHM_4 Doctoral

    branch DKAO_CHM_4 , 1. year of study, winter semester, 0 credits, compulsory-optional

  • Programme DPCP_CHM_4 Doctoral

    branch DPCO_CHM_4 , 1. year of study, winter semester, 0 credits, compulsory-optional

  • Programme DKCP_CHM_4 Doctoral

    branch DKCO_CHM_4 , 1. year of study, winter semester, 0 credits, compulsory-optional

  • Programme AKREDITACE Doctoral, 1. year of study, winter semester, 0 credits, compulsory-optional

Type of course unit

 

Lecture

26 hours, optionally

Teacher / Lecturer

eLearning