Course detail

Binders II

FAST-BJ16Acad. year: 2013/2014

Concise principles of thermodynamics, the first and second law of thermodynamics, heat of formation, chemical equilibrium, Guldberg-Waag law, system out-of-equilibrium, reaction isotherm, State behaviour of liquids, skin effects, cohesive pressure, transport phenomena in liquids, Phase equilibria, one component system, Gibbs law, two components system. Heterogeneous one-, two-, and more components system, solubility of gases in liquids. Solid phase-gas system, solid phase - liquid phase, ternary systems. Electrochemistry, Faraday’s laws, molar conductivity of weak and strong electrolytes, Wheatstone bridge, dissociation and hydrolysis, ionic product of water, galvanic cells. Disperse systems, classification, basic physical properties, coagulation, zeta potential. Reaction kinetics, order and molecularity of reaction, reactions of 1st, 2nd and higher orders, catalysts.
The structure of silicates, Pauling’s principles, basic structural arrangement. Clay minerals, structural arrangement, classification, water bound in clay minerals. Structure and properties of silicate melts, crystallization of melts, glass structures. Heterogeneous equilibria in silicate systems, solid state reactions.
Lectures are complemented by computational and laboratory exercises.

Language of instruction

Czech

Number of ECTS credits

5

Mode of study

Not applicable.

Department

Institute of Technology of Building Materials and Components (THD)

Learning outcomes of the course unit

Brief fundamentals of General Physical Chemistry concerning the state of aggregates, thermodynamics, reaction kinetics, processes on boundaries between phases, sorption effects and basic phenomena of disperse systems – Fundamentals of Physical Chemistry of Silicate Structures, theory of melts and glass, theory of reactions in solid phase.
The student would manage the goal of the subject by acquiring knowledge on the basics of physical chemistry from the field of physical states of substances, thermodynamics, reaction kinetics, processes on the interface boundaries, sorptive effects and basic exposure of the disperse systems, further by knowledge on silicate chemistry from the field of silicate structure, melt and glass theory, theory of reaction in the solid phase.

Prerequisites

Physics, Building Chemistry, Building materials, Geology, Mining and Preparation of Raw Materials, Binding Materials - laboratories

Co-requisites

Properties and Use of Building Materials in Structures

Planned learning activities and teaching methods

Information is presented to students in the form of lectures.

Assesment methods and criteria linked to learning outcomes

Credit – attendance at seminars, submission of finished team tasks, test (pass mark at least 60 %.
The final exam consists of a written and oral part.

Course curriculum

1.Chemical equilibria, the Guldberg-Waag Law, systems outside of equilibrium, reaction isotherm.
2.State behaviour of liquids, surface effects, cohesion pressure, transport processes in liquids.
3.Phase equilibria, one component system, Gibbs Law of phases, system with two components.
4.Heterogeneous one-, two- and more-components systems, solubility of gases in liquids.
5.The systems: solid phase-gas, solid phase-liquid phase, ternary systems.
6.Electrochemistry, Faradays Laws, molar conductivity of weak and strong electrolytes, the Wheatstone´s bridge, dissociation and hydrolysis, ionic product of water, galvanic elements.
7.Disperse systems, division, basic physical properties, coagulation, zeta-potential.
8.Reaction kinetics, order and molecularity of reaction, reactions of 1st, 2nd, and higher orders, catalysts.
9.Structure of silicates, Pauling´s principles, basic structural arrangement.
10.Clay minerals, structural arrangement.
11.Classification of clay minerals, water bond in clay minerals.
12.Structure and the properties of silicate melt.
13.Melt crystallisation, the structure of glass.Heterogeneous equilibria in silicate systems, reactions in solid state.

Work placements

Not applicable.

Aims

Brief fundamentals of General Physical Chemistry concerning the state of aggregates, thermodynamics, reaction kinetics, processes on boundaries between phases, sorption effects and basic phenomena of disperse systems – Fundamentals of Physical Chemistry of Silicate Structures, theory of melts and glass, theory of reactions in solid phase.

Specification of controlled education, way of implementation and compensation for absences

Extent and forms are specified by guarantor’s regulation updated for every academic year.

Recommended optional programme components

conference Binders, cooperation on projects of the Grant Agency of the Czech Republic

Prerequisites and corequisites

Not applicable.

Basic literature

Moore, W.J.: Fyzikální chemie. SNTL Praha, 1981. (CS)

Recommended reading

Kingery, W.D.: Introduction to Ceramics. New York - J. Wiley, 1962. (EN)
EITEL W.: Silicite science. Academie Press N. Y. USA, 1964. (EN)
Brdička R., Dvořák J.: Základy fyzikální chemie. Academia , Praha, 1977. (CS)
Lach,V.,Daňková,M.: Mikrostruktura stavebních látek. VUT v Brně, 1991. ISBN 80-214-0309-8. (CS)
Walter J. Moore: Physical chemistry. Englewood Cliffs, N. J. USA, 1994.

Classification of course in study plans

  • Programme B-P-E-SI Bachelor's

    branch M , 4. year of study, summer semester, compulsory

  • Programme B-K-C-SI Bachelor's

    branch M , 4. year of study, summer semester, compulsory

  • Programme B-P-C-SI Bachelor's

    branch M , 4. year of study, summer semester, compulsory

Type of course unit

 

Lecture

26 hours, optionally

Teacher / Lecturer

Syllabus

1.Chemical equilibria, the Guldberg-Waag Law, systems outside of equilibrium, reaction isotherm.
2.State behaviour of liquids, surface effects, cohesion pressure, transport processes in liquids.
3.Phase equilibria, one component system, Gibbs Law of phases, system with two components.
4.Heterogeneous one-, two- and more-components systems, solubility of gases in liquids.
5.The systems: solid phase-gas, solid phase-liquid phase, ternary systems.
6.Electrochemistry, Faradays Laws, molar conductivity of weak and strong electrolytes, the Wheatstone´s bridge, dissociation and hydrolysis, ionic product of water, galvanic elements.
7.Disperse systems, division, basic physical properties, coagulation, zeta-potential.
8.Reaction kinetics, order and molecularity of reaction, reactions of 1st, 2nd, and higher orders, catalysts.
9.Structure of silicates, Pauling´s principles, basic structural arrangement.
10.Clay minerals, structural arrangement. Classification of clay minerals, water bond in clay minerals.
11.Structure and the properties of silicate melt. Melt crystallisation, the structure of glass.Heterogeneous equilibria in silicate systems, reactions in solid state.

Exercise

26 hours, compulsory

Teacher / Lecturer

Syllabus

1. Conditions of credit awarding prerequisites, laboratory order
2. Transport processes in liquids
3. Phase equilibria - Calculations of, one component system and two components system
4. Molar conductivity of weak and strong electrolytes
5. Reaction kinetics - Calculations of reactions of 1st, 2nd, and higher orders
6. Heterogeneous one-, two- and more-components systems
7. Disperse systems
8. Zeta-potential
9. XRD analysis of silicates
10. Excursion
11. Credit