Publication detail

LiYbCl4(THF)4

RICHTERA, L. JANČÍK, V. HERMANOVÁ, S. KRPOUN, K. THOMPSON-MONTERO, K.

Original Title

LiYbCl4(THF)4

Type

journal article in Web of Science

Language

English

Original Abstract

The title compound, di-[mu]-chlorido-dichlorido-1[kappa]2Cl-tetrakis(tetrahydrofuran)-1[kappa]2O,2[kappa]2O-lithiumytterbium(III), [LiYbCl4(C4H8O)4], was prepared by the reaction of YbCl3(THF)3 with LiCl in THF (THF is tetrahydrofuran). The central motif of the structure is a Yb([mu]-Cl)2Li ring. The Yb atom is hexacoordinated to four Cl atoms and two THF molecules oriented in a trans fashion. The Li atom has a tetrahedral environment and is coordinated to two Cl atoms and two THF molecules. No intermolecular interactions other than van der Waals forces were observed. Two of the THF molecules are disordered over two positions.

Keywords

metal-organic compounds, structure, single-crystal X-ray study, ytterbium

Authors

RICHTERA, L.; JANČÍK, V.; HERMANOVÁ, S.; KRPOUN, K.; THOMPSON-MONTERO, K.

RIV year

2011

Released

8. 5. 2011

Publisher

International Union of Crystallography

Location

England

ISBN

1600-5368

Periodical

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE

Year of study

2011

Number

E67

State

Kingdom of Denmark

Pages from

m700

Pages to

m700

Pages count

13