Publication detail

Synthesis and Crystal Structure of the First Selenonyl Bis(carboxylate) SeO2(O2CCH3)(2)

RICHTERA, L. JANČÍK, V. BARROSO-FLORES, J. NYKEL, P. TOUŽÍN, J. TARABA, J.

Original Title

Synthesis and Crystal Structure of the First Selenonyl Bis(carboxylate) SeO2(O2CCH3)(2)

Type

journal article in Web of Science

Language

English

Original Abstract

Analytically pure selenonyl bis(acetate) SeO2(O2CCH3)(2) was prepared by the reaction of SeO3 with a stoichiometric amount of acetic anhydride in nitromethane; it crystallizes in the monoclinic P2(1)/n space group with one molecule in the asymmetric unit and a = 5.2044(1) angstrom, b = 21.6580(5) angstrom, c = 6.7074(2) angstrom, and = 93.628(2)degrees. The selenium atom binds to two oxo groups and two acetate anions in a distorted tetrahedral geometry. Analysis of the Hirschfeld surface indicated the presence of numerous C-HO interactions.

Keywords

Main group elements; Selenium; Structure elucidation; Hirschfeld surface

Authors

RICHTERA, L.; JANČÍK, V.; BARROSO-FLORES, J.; NYKEL, P.; TOUŽÍN, J.; TARABA, J.

Released

1. 6. 2015

ISBN

1434-1948

Periodical

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Year of study

18

Number

1

State

Federal Republic of Germany

Pages from

2923

Pages to

2927

Pages count

5

BibTex

@article{BUT145353,
  author="RICHTERA, L. and JANČÍK, V. and BARROSO-FLORES, J. and NYKEL, P. and TOUŽÍN, J. and TARABA, J.",
  title="Synthesis and Crystal Structure of the First Selenonyl Bis(carboxylate) SeO2(O2CCH3)(2)",
  journal="EUROPEAN JOURNAL OF INORGANIC CHEMISTRY",
  year="2015",
  volume="18",
  number="1",
  pages="2923--2927",
  doi="10.1002/ejic.201500271",
  issn="1434-1948"
}