Reduction of Irreversible Capacity in Lithium-ion Batteries

conference paper

English

This article is focused on a research of negative materials for Lithium-ion batteries. In the research are considered methods, which can lead to enhance capacity of Lithium-ion batteries. The increase of the battery capacity is based on reduction of irreversible capacity. The majority of Li-ion batteries which are used in this time has negative electrode make from graphite. On interface between electrolyte and graphite electrode originates the SEI layer (Solid-Electrolyte Interphase), this layer is the cause of irreversible capacity of graphite. This layer is indispensable for appropriate battery function but for creating this layer is consumed almost one-third potential capacity of Li-ion cell. In our research we attempted to prepare the material which would reduce these capacity losses. Was designed a concept where n-butyllithium (C4H9Li) reagent behaves as the source of lithium atoms and graphite acts like acceptor of lithium atoms. This process is called „lithiation“, our conception presents n-butyllithium like oxidative reagent which is able to reduce graphite material by Li atoms. Lithium atoms are intercalated between graphite sheets (as at charging process), resulting of this process is new lithiated electrode material which can be used for prepare of negative electrode for Li-ion cells.

Graphite, Lithium, Battery, Capacity, Butyllithium, Iron(III) chloride

LIBICH, J.; VONDRÁK, J.; SEDLAŘÍKOVÁ, M.

2013

20. 3. 2013

Bilbao

978-84-695-6965-8

Sborník mezinárodni konference INTERNATIONAL CONFERENCE ON RENEWABLE ENERGIES AND POWER QUALITY (ICREPQ'13)

2013

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