Publication detail

Trithiocyanurate Complexes of Iron, Manganese and Nickel and Their Anticholinesterase Activity

KOPEL, P. DOLEŽAL, K. LANGER, V. JUN, D. ADAM, V. KUČA, K. KIZEK, R.

Original Title

Trithiocyanurate Complexes of Iron, Manganese and Nickel and Their Anticholinesterase Activity

Type

journal article in Web of Science

Language

English

Original Abstract

The complexes of Fe(II), Mn(II) and Ni(II) with a combination of a Schiff base, nitrogen-donor ligand or macrocyclic ligand and trithiocyanuric acid (ttcH3) were prepared and characterized by elemental analysis and spectroscopies. Crystal and molecular structures of the iron complex of composition [Fe(L1)](ttcH2)(ClO4) EtOH H2O (1), where L1 is Schiff base derived from tris(2-aminoethyl)amine and 2-pyridinecarboxaldehyde, were solved. It was found that the Schiff base is coordinated to the central iron atom by six nitrogens forming deformed octahedral arrangement, whereas trithiocyanurate(1-) anion, perchlorate and solvent molecules are not coordinated. The X-ray structure of the Schiff base sodium salt is also presented and compared with the iron complex. The anticholinesterase activity of the complexes was also studied.

Keywords

trithiocyanuric acid; trimercaptotriazine; crystal structure; complexes; acetylcholinesterase activity; Schiff base

Authors

KOPEL, P.; DOLEŽAL, K.; LANGER, V.; JUN, D.; ADAM, V.; KUČA, K.; KIZEK, R.

RIV year

2014

Released

8. 4. 2014

Publisher

MDPI

ISBN

1420-3049

Periodical

MOLECULES

Year of study

19

Number

4

State

Swiss Confederation

Pages from

4338

Pages to

4354

Pages count

17

URL

http://www.mdpi.com/1420-3049/19/4/4338

Full text in the Digital Library

http://hdl.handle.net/11012/63717

BibTex

@article{BUT109374,
  author="Pavel {Kopel} and Karel {Doležal} and Vratislav {Langer} and Daniel {Jun} and Vojtěch {Adam} and Kamil {Kuča} and René {Kizek}",
  title="Trithiocyanurate Complexes of Iron, Manganese and Nickel and Their Anticholinesterase Activity",
  journal="MOLECULES",
  year="2014",
  volume="19",
  number="4",
  pages="4338--4354",
  doi="10.3390/molecules19044338",
  issn="1420-3049",
  url="http://www.mdpi.com/1420-3049/19/4/4338"
}